Archive for the ‘Solvents’ Category
Isopropyl alcohol
Isopropyl alcohol is readily available. Like acetone, it dissolves a wide range of non-polar compounds. It also evaporates quickly and is relatively non-toxic, compared to alternative solvents. Thus it is used widely as a solvent and as a cleaning fluid, especially for dissolving li pophilic contaminants such as oil.
Examples include cleaning electronic devices such as contact pins (like those on ROM cartridges), magnetic tape and disk heads (such as those in audio and video tape recorders and floppy disk drives), the lenses of lasers in optical disc drives (e.g. CD, DVD) and removing thermal paste from IC packages (such as CPUs.) It is used to clean LCD and glass computer monitor screens (at some risk to the anti-reflection coating on some screens [citation needed]), and used to give second-hand or worn non-vinyl phonograph records newer-looking sheens.
Isopropyl alcohol should not be used to clean vinyl records as it may leach plasticizer from the vinyl making it more rigid [citation needed]). Isopropyl alcohol removes smudges, dirt, and fingerprints from cell phones and PDAs. It is effective at removing residual glue from some sticky labels although some other adhesives used on tapes and paper labels are resistant to it. It can also be used to remove stains from most fabrics, wood, cotton, etc.
Isopropyl alcohol is also used to remove brake fluid traces from hydraulic braking systems, so that the brake fluid (usually DOT 3, DOT 4 or mineral oil) does not contaminate the brake pads, which would result in poor braking. In addition it can also be used to clean paintballs or other oil based products so that they may be reused, commonly known as “repainting”. As a biological specimen preservative, isopropyl alcohol provides a comparatively non-toxic alternative to formaldehyde and other synthetic preservatives. Isopropyl alcohol solutions of 90-99% are optimal for preserving specimens, although concentrations as low as 70% can be used in emergencies.
Disinfecting pads typically contain a 60–70% solution of isopropyl alcohol in water. Isopropyl alcohol is also commonly used as a cleaner and solvent in industry.
Isopropyl alcohol is a major ingredient in “gas dryer” fuel additives. In significant quantities, water is a problem in fuel tanks, as it separates from the gasoline, and can freeze in the supply lines at cold temperatures. It does not remove water from gasoline; rather, the alcohol solubilizes water in gasoline. Once soluble, water does not pose the same risk as insoluble water as it will no longer accumulate in the supply lines and freeze. Isopropyl alcohol is often sold in aerosol cans as a windscreen de-icier.
Isopropyl alcohol is used in keyboard, LCD and laptop cleaning, is sold commercially as a whiteboard cleaner, and is a strong but safer alternative to common household cleaning products.
Isopropyl alcohol is often used in DNA extraction. It is added to a DNA solution in order to precipitate the DNA into a ‘pellet’ after centrifuging the DNA. This is possible because DNA is insoluble in isopropyl alcohol.
Isopropyl alcohol is used as a water-drying aid for the prevention of otitis externa, better known as swimmer’s ear
M A T E R I A L S A F E T Y D A T A S H E E T
SECTION 1. Product and Company Identification
ISOPROPYL ALCOHOL 99%
Product Code: HH-ISOAL-99
SECTION 2. Composition/Information on Ingredients
ISOPROPYL ALCOHOL 99%
Hazardous Components (Chemical Name) CAS # Concentration
1. Isopropyl alcohol {sec-Propyl alcohol; IPA; 2-Propanol} 67-63-0 99.0 - 100.0 %
OSHA PEL ACGIH TLV ACGIH STEL
1. 400 ppm 200 ppm 400 ppm
SECTION 3. Hazards Identification
ISOPROPYL ALCOHOL 99%
Emergency Overview
No data available.
Route(s) of Entry: Inhalation? Yes , Skin? Yes , Eyes? Yes , Ingestion? Yes
Potential Health Effects (Acute and Chronic)
No data available.
Carcinogenicity: NTP? N.A. , IARC Monographs? N.A. , OSHA Regulated? N.A.
Carcinogenicity/Other Information
No data available.
Signs and Symptoms Of Exposure
Giddiness, headache, dizziness, nausea and drowsiness.
Medical Conditions Generally Aggravated By Exposure
No data available.
Additional Hazards Information
LD 50/ LC 50: Acute dermal Rabbit 1300 mg/kg; Acute inhalation Rat (8 hours) 12000 ppm.
SECTION 4. First Aid Measures
ISOPROPYL ALCOHOL 99%
Emergency and First Aid Procedures
IF SWALLOWED: Do NOT induce vomiting. Drink two glasses of water and contact physician or Poison Control Center. Keep at rest. If vomiting occurs spontaneously, keep head below hips to prevent aspiration of liquid into lungs.
IF INHALED: Remove patient to fresh air and provide oxygen if breathing is difficult. Give artificial respiration if not breathing. Get medical attention.
IF IN EYES: Flush with water for 15 minutes while periodically holding eyelids open.
IF ON SKIN: Wash with soap and water. Remove contaminated clothing and shoes; do not reuse until cleaned. If persistent irritation occurs, get medical attention.
Note to Physician
No data available.
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SECTION 5. Fire Fighting Measures
ISOPROPYL ALCOHOL 99%
Flash Pt: 55.00 F Method Used: TCC
Explosive Limits: LEL: 2.5% UEL: 12.1%
Extinguishing Media
Water, fog, dry chemical, CO2, Alcohol foam
Fire Fighting Instructions
Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Water may be ineffective for fire fighting. Use water spray to keep fire-exposed containers cool and to protect personnel. If a leak or spill has not ignited, use water spray to disperse the vapors. Either allow fire to burn under controlled conditions or extinguish with alcohol-type foam and dry chemical. Try to cover liquid spills with foam.
Flammable Properties and Hazards
Flammable liquid. Vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Run-off from fire control may cause pollution.
Hazardous Combustion Products
No data available.
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SECTION 6. Accidental Release Measures
ISOPROPYL ALCOHOL 99%
Steps To Be Taken In Case Material Is Released Or Spilled
WARNING!! Flammable. Eliminate all ignition sources. Handling equipment must be grounded to prevent sparking.
**LARGE SPILLS** Evacuate hazard area of unprotected personnel. Wear appropriate respirator and protective clothing. Shut off source of leak only if safe to do so. Dike and contain. If vapor cloud forms, water fog may be used to suppress; contain run-off. Remove with vacuum trucks or pump to storage/salvage vessels. Soak up residue with an absorbent such as clay, sand or other suitable material; place in non-leaking containers for proper disposal. Flush area with water to remove trace residue; dispose of flush solution as above.
**SMALL SPILLS** Take up with an absorbent material and place in non-leaking containers; seal tightly for proper disposal.
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SECTION 7. Handling and Storage
ISOPROPYL ALCOHOL 99%
Precautions To Be Taken in Handling
Keep liquid and vapor away from heat, sparks and flame. Surfaces that are sufficiently hot may ignite even liquid product in the absence of sparks or flame. Extinguish pilot lights, cigarettes and turn off other sources of ignition prior to use and until all vapors are gone. Empty containers retain residue (liquid and/or vapor) and can be dangerous.
Precautions To Be Taken in Storing
Keep out of direct sunlight. Store in cool, dry area. Store in tightly sealed containers.
Other Precautions
KEEP OUT OF REACH OF CHILDREN. Do not pressurize, cut , weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition. Aluminum containers are not recommended for storage.
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SECTION 8. Exposure Controls/Personal Protection
ISOPROPYL ALCOHOL 99%
Respiratory Equipment (Specify Type)
Self-contained breathing apparatus
Eye Protection
Goggles
Protective Gloves
Rubber gloves
Other Protective Clothing
Protective clothing during fire fighting
Engineering Controls (Ventilation etc.)
Local ventilation sufficient if well ventilated.
Work/Hygienic/Maintenance Practices
MInimize skin contact. Wash with soap and water before eating, drinking, smoking or using toilet facilities.
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SECTION 9. Physical and Chemical Properties
ISOPROPYL ALCOHOL 99%
Physical States: [ ] Gas , [ X ] Liquid , [ ] Solid
Boiling Point: 179.90 F
Melting Point: No data.
Specific Gravity (Water = 1): .786 at 68.0 F
Density: 2.1
Vapor Pressure (vs. Air or mm Hg): 32.8 at 68.0 F
Vapor Density (vs. Air = 1): 2.1
Evaporation Rate (vs Butyl Acetate=1): 1.4
Solubility in Water: No data.
Percent Volatile: 99.0 % by volume.
Saturated Vapor Concentration: No data.
Viscosity: No data.
pH: neutral
Appearance and Odor
Colorless liquid, alcohol-type odor
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SECTION 10. Stability and Reactivity
ISOPROPYL ALCOHOL 99%
Stability: Unstable [ ] Stable [ X ]
Conditions To Avoid – Instability
Exposure to sparks or flame. Avoid storing or handling of this product at temperatures above 120 deg F.
Incompatibility – Materials To Avoid
Alkylene oxides, acid anhydrides, isocyanates, organometallic contaminates, concentrated nitric and sulfuric acids, alkanolamines, austics, amines, ammonia, reactive halogenated compounds, e.g. muriatic acid and acetyl chloride, organic acids, halogens, phosphorous trichloride,aldehydes, monomers, polymerizable esters.
Hazardous Decomposition Or Byproducts
Carbon monoxide and unidentified organic compounds may be formed during combustion.
Hazardous Polymerization: Will occur [ ] Will not occur [ X ]
Conditions To Avoid – Hazardous Polymerization
No data available.
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SECTION 11. Toxicological Information
ISOPROPYL ALCOHOL 99%
No data available.
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SECTION 12. Ecological Information
ISOPROPYL ALCOHOL 99%
No data available.
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SECTION 13. Disposal Considerations
ISOPROPYL ALCOHOL 99%
Waste Disposal Method
Place in a disposal facility approved under RCRA regulations for hazardous waste. Use non-leaking containers, seal tightly and label properly. Assure compliance with local, state and federal regulations.
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SECTION 14. Transport Information
ISOPROPYL ALCOHOL 99%
DOT Proper Shipping Name
No data available.
Additional Transport Information
No data available.
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SECTION 15. Regulatory Information
ISOPROPYL ALCOHOL 99%
No data available.
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SECTION 16. Other Information
ISOPROPYL ALCOHOL 99%
Supercedes Revision 07/19/2005
HMIS Hazard Ratings:
Health:
2
Flammability: 3
Reactivity: 0
Protection: H
Minimal: 0
Slight: 1
Moderate: 2
Serious: 3
Extreme: 4
The information and data herein are believed to be accurate and have been compiled from sources believed to be reliable. It is offered for your consideration, investigation and verification.
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SECTION 16. Other Information
ISOPROPYL ALCOHOL 99%
Supercedes Revision 07/19/2005
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SPECIFICATION OF ACETONE
CHARACTERISTICS?ANALYSIS REPORT?SPECIFICATIONS
Colour (H.U)???? 5???10 Max
Relative Density at 27/27*C 0.7850???0.7840 to 0.7860
Distillation Range??? Agree with specn?Shall distil within 1*c?
Including 56.1*C
Water Content(wt%)?? 0.20???0.40 max
Residue on.evaporation (gms/100ml)0.0005??0.002 max
Acidity as CH3 COOH?0.0008???0.002 max
Alkalinity??Pass???To pass the test
Permanganate Test?Pass???To pass the test
30 Minits Min)
Alcoholic impurities?Pass???To pass the test
Miscibility with water?Agree with Specn??Shall show no turbidity on Mixing with distilled water at 27*C
Assay ( wt %)?? 99.80???99.5 Min
Testing methods 1-10 are as per IS:170-1986
The product conforms to the specifications given under IS:170-1986
SPECIFICATION OF N-BUTANOL
Characteristics?? ??Units?? Results????????? Specification
Appearance????? ??W%?? Clear colorless Liquid??? Clear colorless Liquid?
N-Butanol? ?W%?? 99.58?????????? 99.50
Water Content? ??W%???? 0.1????????????? ????????? 0.1?
Acidity as CH3COOH ?W%???? 0.006?????????? 0.01
Aldehyde content? ?W%??? 0.008?????????? 0.05
Sulphuric Acid Colour?????? Apha?15??????????????????????? 25 Max
Residue on Evaporation???? Gm/100ml 0.001?????????? 0.002?
SPECIFICATION OF BENZENE
Relative density 15.6/15/6 deg.C??? : 0.879-0.886
Distillation range 1-96%??????????????? ??? : 0.6(incl.80.1C)
Residue on evaporation mg/100ml?: 5
Total Sulphur, ppm max?????????????????? : 2.0
H2S & Mercaptans??????????????????????????? : -ve
Crystallization point C Min??????????????? : 5.3
Non-aromatics, ppm Max???????????????? : 500
Purity(GLC Method), Min (%)??????? : 99.93
?
SPECIFICATION OF ETHYL ACETATE
Molecular Weight??: 88.10
Specific Gravity at20/20*C?: 0.8975 to 0.9018
Ethyl Acetate Conternt Min?: 97& by weight
Acidity as acetic acid Max?? ?: 0.02% by weight
Water content???: Miscible without turbidity with 19?
volumes of 60*API gasoline at 20*C
Distillation at 760mm HG
IBP Min???????????????????????? : 74*C
DP Max??????? ???????????????? : 80*C
Colour,platinum-Cobalt
Scale, max?????????????????????: 15
Suspended matter?????? : Subs antially free
