Caustic Soda Lye

Specifications :

Sodium Hydroxide NaOH – 48% +/- 2% by wt.

Sodium Carbonate Na2CO3 – 0.5% by wt.

Max Sodium Chloride NaCl -  350ppm by wt.

MaxSodium sulphate Na2SO4 – 200ppm by wt.

MaxSodium Chlorate NaClO3 – 20 ppm by wt.

MaxIron Fe+2 – 10 ppm by wt. MaxNickel Ni+2 – 1.5 ppm by wt.

MaxCopper Cu+2 – 2ppm by wt. MaxMaganses Mn+2 – 2 ppm by wt.

MaxSIlicate SiO2 – 10 ppm by wt.Max

 GENERAL DESCRIPTION

Sodium Hydroxide, commonly known as caustic soda, lye, or sodium hydrate, is a caustic compound, which attacks organic matter. (Caustic soda is sodium hydroxide, caustic potash is potassium hydroxide and silver nitrate is lunar caustic.) Caustic soda is available commercially in various white solid forms and as solutions of various concentrations in water. It is very soluble in water, alcohol, and glycerin and absorbs carbon dioxide and moisture from the air. Sodium hydroxide is prepared by the reaction of sodium carbonate (soda) in concentrated solution form with calcium hydroxide (slaked lime). But the principal method for its manufacture is by the electrolysis of brine. (the two current technologies are the diaphragm and the membrane).

The electrolyte is saturated brine (about 25% aqueous sodium chloride). The chloride ion is oxidized at the anode to chlorine gas. Chlorine gas is a co product. Sodium hydroxide is a strong base and inexpensive which find many applications in the chemical industry. Sodium hydroxide provides functions of neutralization of acids, hydrolysis, and condensation. Specification and replacement of other groups in organic compounds of hydroxyl ions. The major use of sodium hydroxide is as a chemical and in the manufacture of other chemicals. It is used in textile industry. Sodium hydroxide is used mainly for two processes in textile manufacture. Mercerizing of fibre with sodium and hydroxide solution enables greater tensional strength and consistent luster. It also removes waxes and oils from fibre to make the fibre more receptive to bleaching and dying. Sodium hydroxide is also used in the production of viscose rayon. Cellulose is extracted from pulp using sodium hydroxide and subsequently treated with high purity sodium hydroxide to produce soda cellulose.

Further chemical treatment results in a rayon fibre. This is a declining market due to the competition from synthetic (i.e. petrochemical) fibres. It is used in making paper and pulp. Sodium hydroxide aids separation of cellulose fibres from lignin; this breaks down wood into pulp. Sodium hydroxide also helps bleach paper to required whiteness and brightness. In alumina production industry, a strong alkali solution separates pure alumina from bauxite ore. Alumina is then recovered through precipitation and finally, calcinations. Sodium hydroxide is also widely used in making soaps and detergents; Sodium hydroxide was originally used for soap manufacture, but now has a wider variety of functions.

As well as an extractant and refining agent for certain oils, sodium hydroxide is used to produce active agents, or builders in modern synthetic detergents. Sodium Hydroxide is used for sodium hypochlorite, which is used as a household bleaches, and disinfectant and for sodium phenolate used in antiseptics and for the manufacture of Aspirin.

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE    Clear solution colourless

MELTING POINT      12 C

BOILING POINT       140 C

SPECIFIC GRAVITY             1.53

SOLUBILITY IN WATER      Completely miscible

PH       14

VAPOR DENSITY (AIR=1)  

AUTOIGNITION       

NFPA RATINGS        Health: 3; Flammability: 0; Reactivity: 1

REFRACTIVE INDEX           

FLASH POINT           Not considered being a fire hazard

STABILITY     Stable under ordinary conditions

APPLICATIONS

Direct application, (pulp and paper, soaps and detergents, aluminia, petroleum, textiles,

Water treatment,); organic chemicals, (propylene oxide, polycarbonate, ethylene amines,

Epoxy resins,); inorganic chemicals, (sodium/calcium hypo chlorite, sulfur-containing

Compounds, sodium cyanide,)

SALES SPECIFICATION

APPEARANCE           Colorless, odorless viscous solution

NaOH  48.0 – 51.0%

CHLORIDES (NaCl)   150ppm max

IRON (Fe)       15-ppm max

CARBONATES (Na2CO3)    0.2% max

SULPHATES (Na2SO4)         20-ppm max

SILICA (SiO2)            50-ppm max

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